Water rich in dissolved ancient calcium carbonates, commonly known as hard water, is the most common reason for the freshwater reservoir effect. Although it has been known for more than 60 years, it is still less well-recognized by archaeologists than the marine reservoir effect.
Levels of carbon-14 become difficult to measure and compare after about 50,000 years (between 8 and 9 half lives; where 1% of the original carbon-14 would remain undecayed).
The question should be whether or not carbon-14 can be used to date any artifacts at all? There are a few categories of artifacts that can be dated using carbon-14; however, they cannot be more 50,000 years old.
Libby and coworkers, and it has provided a way to determine the ages of different materials in archeology, geology, geophysics, and other branches of science.
Some examples of the types of material that radiocarbon can determine the ages of are wood, charcoal, marine and freshwater shell, bone and antler, and peat and organic-bearing sediments.
When these energetic neutrons collide with a nitrogen-14 (seven protons, seven neutrons) atom it turns into a carbon-14 atom (six protons, eight neutrons) and a hydrogen atom (one proton, zero neutrons).